High Temperature Peroxide Bleaching of Mechanical Pulps from Spruce, 2007 International Mechanical Pulping Conference

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High-temperature (HT)-peroxide bleaching of a thermomechanical pulp made of Norwegian spruce was investigated; to that end, one-stage reference bleaching at 70°C and one- and two-stage bleaching at 105°C at different total alkali charges (TAs) using a wing defibrator as a mixer were performed.

Two-stage HT peroxide bleaching produces a brighter pulp than one-stage HT peroxide bleaching does. The TA should be kept low (10–15 kg/t) and the total alkali/peroxide ratio should be low in the first stage to minimize the COD load and obtain higher residual peroxide. Increased TA does not improve brightness. The bleaching time in HT bleaching at 105°C can be short, since the maximum brightness is reached after only 2.5 min.

Preimpregnation of the pulp with hydrogen peroxide before a two-stage alkali addition can produce a pulp with a brightness and residual peroxide comparable to those obtained in conventional one-stage peroxide bleaching at the same hydrogen peroxide charge and at a low TA. The COD load was, however, higher than in conventional bleaching.