Critical parameters for tall oil separation I: The importance of ration of fatty acids to rosin acids, TAPPI Journal September 2019



Application: Controlling the ratio of fatty acids to rosin acids in kraft pulping can significantly affect the tall oil separation and improve its yield and quality.

TAPPI conference proceedings and presentations, technical papers, and publication articles provide technical and management data and solutions on topics covering the Pulp, Paper, Tissue, Corrugated Packaging, Flexible Packaging, Nanotechnology and Converting Industries.

Simply select the quantity, add to your cart and your conference paper, presentation or article will be available for immediate download.
Author: Ioannis Dogaris, Mikael E. Lindström, and Gunnar Henriksson
Critical parameters for tall oil separation I: The importanc
ABSTRACT: Tall oil is a valuable byproduct in chemical pulping of wood, and its fractions have a large spectrum of applications as chemical precursors, detergents, and fuel. High recovery of tall oil is important for the economic and environmental profile of chemical pulp mills. The purpose of this study was to investigate critical parameters of tall oil separation from black liquor. To investigate this in a controlled way, we developed a model test system using a “synthetic” black liquor (active cooking chemicals OH- and HS- ions), a complete process for soap skimming, and determination of recovered tall oil based on solvent extraction and colorimetric analysis, with good reproducibility. We used the developed system to study the effect of the ratio of fatty acids to rosin acids on tall oil separation. When high amounts of rosin acids were present, tall oil recovery was low, while high content of fatty acids above 60% significantly promoted tall oil separation. Therefore, manipulating the content of fatty acids in black liquor before the soap skimming step can significantly affect the tall oil solubility, and hence its separation. The findings open up chemical ways to improve the tall oil yield.
30.00

New Releases

 

Kraft Recovery Boilers, Third Edition  


Sponsored by the Recovery Boiler Program R&D Subcommittee of the American Forest & Paper Association (AF&PA) and published by TAPPI Press.


Purchase


 

Handbook For Pulp and Paper Technologists (The SMOOK Book), Fourth Edition

The best-selling text to introduce the entire technology of pulp and paper manufacture.

Purchase

 

Guidelines for Safe Assessment and Operation of Yankee Dryers  


A project of the Yankee Dryer Safety & Reliability Committee.

Purchase

 

Check our newest additions.


TAPPI Press offers some of the most in-depth resources and references for the forest products and related industries. 

See More

   
 

Available for Purchase – Conference Proceedings


TAPPI maintains a record of key conference papers, presentations, and other conference publications, available for purchase in a variety of formats.

See More