Dissolution of wood components during hot water extraction of spruce, TAPPI Journal May 2023



Application: The focus of this study is the mechanistic understanding of autohydrolysis and revealing the structural changes that occur in hemicelluloses and cellulose. The provided information could be used when designing and tuning pretreatment steps aimed at recovery of hemicelluloses prior to pulping.

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Author: Joanna Wojtasz-Mucha, Merima Hasani, and Hans Theliander
Dissolution of wood components during hot water extraction o
ABSTRACT: The purpose of this study was to investigate the autohydrolysis of softwood, which is the main chemical operation in both hot water extraction and steam explosion. Control of the process and monitoring its course were ensured by the careful choice of experimental setup and conditions: a milled spruce material was extracted in a small flow-through reactor to minimize degradation of the dissolved material and to enable analysis of the resulting liquors extracted at selected time points. The obtained liquid and solid fractions were analyzed for sugar composition and acetic acid concentration. The results showed that partially degraded hemicelluloses were extracted; hemicelluloses side chains were cleaved off and detected as monomers, while deacetylation was limited. Chain scissions of cellulose were observed as a result of autohydrolysis.
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