Factors affecting phosphorus uptake/dissolution during slaking and causticizing, TAPPI Journal March 2024

 


Application: Phosphorus that enters pulp mills with the wood to the digester is ultimately purged from the mill with the purged lime mud. This work can be used by mills to predict how much lime needs to be purged if considering higher phosphorus inputs to the mill through combustion of biomass fuels in the lime kiln or combustion of bio-sludge with black liquor in the recovery boiler.

TAPPI conference proceedings and presentations, technical papers, and publication articles provide technical and management data and solutions on topics covering the Pulp, Paper, Tissue, Corrugated Packaging, Flexible Packaging, Nanotechnology and Converting Industries.

Simply select the quantity, add to your cart and your conference paper, presentation or article will be available for immediate download.
Author: Maryam Sadegh Mousavi, and Nikolai DeMartini
Factors affecting phosphorus uptake/dissolution during slaki
ABSTRACT: Hydroxide is regenerated in the recovery cycle of kraft pulp mills by the addition of lime (CaO) to green liquor. Phosphate in green liquor can react with the lime during slaking/causticizing. Total titratable alkali (TTA), sulfidity, the concentration of phosphate in the green liquor, temperature, and the liming ratio were all variables explored in this work to determine their influence on phosphorus uptake and dissolution. Experiments were also run in which the lime was slaked before being added to the green liquor to separate reactions with phosphate during slaking and reactions that occur during causticizing. Both reburnt lime and technical grade CaO were used. The experiment results indicate that phosphorus primarily reacts with slaked lime (Ca(OH)2), and that the final concentration of phosphate in the white liquor at the end of slaking and causticizing is nearly independent of the initial concentration of phosphorus and only mildly dependent on the carbonate concentration in the green liquor. There do appear to be differences in the rate at which phosphate reacts with reburnt lime and technical grade CaO, though the reason for this was not determined.
0.00

New Releases

TAPPI PRESS Catalog eBook 2024


Experience the Power of Publications in the 2024 TAPPI Press Catalog


Open
 

Kraft Recovery Boilers, Third Edition  


Sponsored by the Recovery Boiler Program R&D Subcommittee of the American Forest & Paper Association (AF&PA) and published by TAPPI Press.


Purchase
 

Handbook For Pulp and Paper Technologists (The SMOOK Book), Fourth Edition

The best-selling text to introduce the entire technology of pulp and paper manufacture.

Purchase
 

Guidelines for Safe Assessment and Operation of Yankee Dryers  


A project of the Yankee Dryer Safety & Reliability Committee.

Purchase
 

Check our newest additions.


TAPPI Press offers some of the most in-depth resources and references for the forest products and related industries. 

See More
   
 

Available for Purchase – Conference Proceedings


TAPPI maintains a record of key conference papers, presentations, and other conference publications, available for purchase in a variety of formats.

See More